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Extension

Secondary Nutrients

Essential plant nutrients, chemical symbols and sources 

Mostly from Air and Water (non-mineral)
From Soil and/or Fertilizers (Mineral)
ElementSymbolElementSymbol
CarbonCNitrogenN
HydrogenHPhosphorusP
OxygenOPotassiumK


CalciumCa


MagnesiumMg


SulfurS


IronFe


MangeaneseMn


ZincZn


CopperCu


BoronB


MolybdenumMo


ChlorineCl

The essential plant nutrients may be grouped into three categories.

They are as follows:

  1. Primary nutrients - nitrogen, phosphorus and potassium
  2.  Secondary nutrients - calcium, magnesium and sulfur
  3. Micronutrients - iron, manganese, zinc, copper, boron, molybdenum, and chlorine 
Secondary Elements
Calcium (Ca)Calcium fertilizers are not usually needed in Oklahoma. Common sources of supplemental Ca are lime and gypsum.
Calcium Carbonate (Lime)20-40% Ca
Calcium Sulfate (Gypsum)23% Ca, (18.6% Sulfur)
Normal Superphosphate 22% Ca, (20% P2O5, 12% Sulfur)


Magnesium (Mg)The most common sources of magnesium are magnesium sulfate and dolomitic lime.
Magnesium Oxide 52% Mg
Magnesium Sulfate16% Mg
Potassium - Magnesium Sulfate (Sul-Po-Mag, K-Mag)11% Mg, (22% K2O, 22% Sulfur)
Dolomitic Limestone (varies)12% Mg


Sulfur (S)Sulfur is most available when supplied in the highly water soluble sulfate form.  Ag. sulfur (elemental sulfur) can be used, but requires biological oxidation over time to convert the elemental form to available sulfate.
Calcium Sulfate (Gypsum)17% S (22% Ca)
Potassium Sulfate17% S
Sulfate of Potash, Magnesia22% S
Ammonium Sulfate24% S
Normal Superphosphate12% S
Ammonium Thiosulfate26% S


Boron (B)A sodium borate (solubor) containing about 20% B is the source of B most commonly used in liquids.  Boric acid and other soluble forms containing between 14 to 20% B are also suitable for liquid mixes.
Borax 11.3% B

Exerts from Oklahoma Soil Fertlity Handbook 2006 (Zhang and Raun 2006).

Micronutrients

Zinc (Zn), Iron (Fe), Copper (Cu), and Manganese (Mn):

The micronutrient elements can be discussed as a group since their sources are somewhat similar.  Industry separates the compounds into two general categories; inorganic and organic.  Inorganic include sulfates, oxides, carbonates and chlorides.  The term organic applies primarily to chelated products and some sequestered materials.  Most chelates, and particularly liquid products, can be mixed with liquid without difficulty. 

Micronutrients

Zinc


Zinc Sulfate25-36% Zn

Zinc Oxide 50-80% Zn

Zinc Chloride48% Zn

Zinc Chelate9-14.5% Zn
Iron


Ferrous Sulfate20.1% Fe

Ferric Sulfate19.9% Fe

Ferrous Ammonium Sulfate14.2% Fe

Ferric Chloride34.4% Fe

Iron Chelate10% Fe
Copper


Copper Sulfate 25% Cu
Manganese


Manganese Sulfate23-28% Mn
Molybdenum (Mo)Ammonium molybdate is satisfactory for liquids.  Sodium molybdate can also be used although it is less soluble than ammonium molybdate.  Since Mo is applied in ounces per acre, liquids are ideal for getting even distribution.

Sodium Molybdate39.7% Mo

Ammonium Molybdate54.3% Mo
ChlorineChlorine has only recently been found deficient in Oklahoma soils.  The deficiency in wheat on deep sandy soils near Perkins, OK can be corrected using muriate of potash (0-0-60).  This is the common source of potassium, which is usually also deficient in these sandy soils.

Exerts from Oklahoma Soil Fertlity Handbook 2006, (Zhang and Raun 2006).

A table describing the symptoms shown in a plant correlated with the nutrient it is deficient in.

Table 4.11 from Oklahoma Soil Fertility Handbook 2006, (Zhang and Raun 2006).